OPTIMALISASI PROSES TRANSESTERIFIKASI DALAM PEMBUATAN BIODIESEL DARI MINYAK JELANTAH MENGGUNAKAN KATALIS KALSIUM OKSIDA

Authors

  • Ronan Fadly Qoshiro Politeknik Negeri Sriwijaya Palembang Author
  • Yohandri Bow Politeknik Negeri Sriwijaya Palembang Author
  • Rima Daniar Politeknik Negeri Sriwijaya Palembang Author

DOI:

https://doi.org/10.5281/zenodo.20118890

Keywords:

Biodiesel, Transesterification, Used Cooking Oil, CaO, Yield

Abstract

Used cooking oil is household waste that is often disposed of directly into the environment, thus potentially polluting water and soil. On the other hand, used cooking oil contains triglycerides which can still be used as raw material for biodiesel through the transesterification process. The global energy crisis and increasing awareness of the environmental impact of fossil fuels have driven the development of biodiesel as an environmentally friendly and renewable alternative energy source. This study aims to optimize the process parameters for making biodiesel based on used cooking oil using calcium oxide (CaO) catalyst with a concentration of 0.5 N. The research variations included reaction times of 40, 60, and 80 minutes and stirring speeds of 200, 300, and 400 rpm at a reaction temperature of 50 °C and a molar ratio of methanol to oil of 6:1. The results showed that reaction time and stirring speed significantly influenced the yield percentage and quality of biodiesel. The optimum conditions were obtained at a reaction time of 40 minutes and a stirring speed of 400 rpm, with a yield of 82.61%. The resulting biodiesel has physical characteristics according to SNI 7182:2015 standards, including a density of 870–889 kg/m³, a viscosity of 0.30–0.41 cP, a flash point above 139 °C, and a cetane number of up to 51.1. This indicates that the use of CaO catalyst is effective in improving the performance of the transesterification reaction and producing good-quality biodiesel. Furthermore, operational parameters such as reaction time and stirring speed have been shown to play a critical role in determining conversion efficiency and biodiesel quality. Overall, this research confirms the potential of used cooking oil as an economical renewable energy source and an environmental solution for waste management. The process also has the potential to be further developed for larger- scale production and community applications.

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References

Abdulkareem, A. N., & Nasir, N. F. (2022). Biodiesel Production from Canola Oil Using TiO2CaO as a Heterogenous Catalyst. Journal of Advanced Research in Fluid Mechanics and Thermal Sciences, 93(2), 125–137. https://doi.org/10.37934/arfmts.93.2.125137

Abdullah, M. H., Riyanto, O. A. W., & Wulan, D. P. I. B. S. (2021). Optimization of esterification and transesterification process for biodiesel production from used cooking oil. Journal of Research and Technology (JRT), 7(2), 207–216. https://doi.org/10.55732/jrt.v7i2.432

Asriza, R., & Fabiani, V. (2018). Transesterifikasi minyak jelantah menggunakan katalis CaO dari cangkang siput gonggong. Prosiding Seminar Nasional Penelitian & Pengabdian Pada Masyarakat, 1–3.https://doi.org/10.33019/snppm.v2i0.621

Azhari, A., Mulyawan, R., Nasrul Z. A., Hakim, L., & Nur Azura Lubis. (2023). Pembuatan biodiesel dari campuran minyak jarak kepyar (Ricinus communis) dengan minyak jelantah menggunakan katalis CaO limbah cangkang kerang darah (Anadara granosa). Jurnal Teknologi Kimia Unimal, 12(1). https://doi.org/10.29103/jtku.v12i1.11797

Cerón Ferrusca, M., Romero, R., Martínez, S. L., Ramírez-Serrano, A., & Natividad, R. (2023). Biodiesel Production from Waste Cooking Oil: A Perspective on Catalytic Processes. Processes, 11(7). https://doi.org/10.3390/pr11071952

Dimawarnita, F., Arfiana, A. N., Mursidah, S., Maghfiroh, S. R., & Suryadarma, P. (2021). Produksi Biodiesel Berbasis Minyak Nabati Menggunakan Aspen Hysys. Jurnal Teknologi Industri Pertanian, 31(1), 98–109. https://doi.org/10.24961/j.tek.ind.pert.2021.31.1.98

Hussein, M., & Idris, M. (2024). Experimental Studies of Flame Points and Biodiesel Viscosity Produced from Waste Cooking Oil. International Research Journal of Advanced Technology, Management and Applied Science (IRAJTMA), 3(1), 86–92.

Jain, S., Kumar, N., Singh, V. P., Mishra, S., Sharma, N. K., Bajaj, M., & Khan, T. M. Y. (2023). Transesterification of Algae Oil and Little Amount of Waste Cooking Oil Blend at Low Temperature in the Presence of NaOH. Energies, 16(3). https://doi.org/10.3390/en16031293

Kumar, A., Bhayana, S., Singh, P. K., Tripathi, A. D., Paul, V., Balodi, V., & Agarwal, A. (2025). Valorization of used cooking oil: challenges, current developments, life cycle assessment and future prospects. In Discover Sustainability (Vol. 6, Issue 1). Springer International Publishing. https://doi.org/10.1007/s43621-025-00905-7

Kurniawan, E., & Nurhayati, N. (2020). Transesterfication Process of Waste Cooking Oil Catalyzed by Na/CaO Derived from Blood Clam (Anadara Granosa) Shells. EKSAKTA: Journal of Sciences and Data Analysis, 1(1), 1–6. https://doi.org/10.20885/eksakta.vol1.iss1.art1

Lesbani, A., Kurniawati, M. R., & Mohadi, R. (2013). Produksi biodiesel melalui reaksi transesterifikasi minyak jelantah dengan katalis cangkang kerang darah (Anadara granosa) hasil dekomposisi. Cakra Kimia (Indonesian E-Journal of Applied Chemistry), 1(2), 1–7. http://repository.unsri.ac.id/id/eprint/21578

Maneerung, T., Kawi, S., Dai, Y., & Wang, C. H. (2016). Sustainable biodiesel production via transesterification of waste cooking oil by using CaO catalysts prepared from chicken manure. Energy Conversion and Management, 123, 487–497. https://doi.org/10.1016/j.enconman.2016.06.071

NguyenThi, T. X., Bazile, J.-P., & Bessières, D. (2018). Density measurements of waste cooking oil biodiesel and diesel blends over extended pressure and temperature ranges. Energies, 11(5), 1212. https://doi.org/10.3390/en11051212

Padil, P., Wahyuningsih, S., & Awaluddin, A. (2012). Pembuatan Biodiesel dari Minyak Kelapa melalui Reaksi Metanolisis Menggunakan Katalis CaCO3 yang dipijarkan. Jurnal Natur Indonesia, 13(1), 27. https://doi.org/10.31258/jnat.13.1.27-32

Pasaribu, A. T., Sigit Lestari, R. A., & Firyanto, R. (2023). Pembuatan Biodiesel Dengan Cara Adsorpsi Kulit Pisang Kepok Dan Transesterifikasi Dari Minyak Goreng Bekas. CHEMTAG Journal of Chemical Engineering, 3(2), 40.https://doi.org/10.56444/cjce.v3i2.3151

Ridho, A. R., Prasetyo, D. A., Susmiati, Y., & Ulma, Z. (2023). Analysis of biodiesel process from waste cooking oil using heterogeneous catalyst field snail shell (Pila ampullacea). Jurnal Polimesin, 21(3), –. Lhokseumawe: Politeknik Negeri Lhokseumawe. https://e-jurnal.pnl.ac.id/polimesin/article/view/4287

Ritonga, F. Y., Hasmita, I., & Sartika, Z. (2021). Pengaruh Waktu Kontak Dan Ukuran Adsorben Pada Pemurnian Minyak Goreng Bekas Menggunakan Cangkang Kerang Sebagai Bahan Baku Biodiesel The Effect of Contact Time and Adsorbent Size on the Purification of Waste Cooking Oil Using Seashells as Raw Material fo. 2(3), 3–6.

Sangadah, K., & Kartawidjaja, J. (2020). TRANSESTERIFIKASI MINYAK GORENG BEKAS MENJADI BIODIESEL MENGGUNAKAN KATALIS CaO CANGKANG SIPUT GONGGONG (Strombus canarium) DIIMPREGNASI KOH: VARIASI WAKTU DAN TEMPERATUR REAKSI. Orphanet Journal of Rare Diseases, 21(1), 1–9.

Suryanto, S., Abadi, S., Amanah, B., & Wahyudin, W. (2021). Rancang Bangun Mesin Produksi Biodiesel Sistem Kontinyu Kapasitas 400 Liter/Jam. Jurnal Teknik Mesin Sinergi, 18(2), 213–223. https://doi.org/10.31963/sinergi.v18i2.2645

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Published

2026-05-11